A three-dimensional microporous metal-metalloporphyrin framework.

نویسندگان

  • Zhiyong Guo
  • Dan Yan
  • Hailong Wang
  • Daniel Tesfagaber
  • Xinle Li
  • Yusheng Chen
  • Wenyu Huang
  • Banglin Chen
چکیده

A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.

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عنوان ژورنال:
  • Inorganic chemistry

دوره 54 1  شماره 

صفحات  -

تاریخ انتشار 2015